rac-BINAP, min 97%
Synonym: (±)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (±)-BINAP,
Molecular Formula: C44H32P2
Color and Form:white to light-yellow xtl.
MP: 283-286 °C (lit.)
Storage: Keep container tightly closed in a dry and well-ventilated place.
Store under inert gas. Air and light sensitive. Keep in a dry place. Non Combustible Solids
Precautions for safe handling:
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
Ligand employed in a palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines.Used with Cu (II) to catalyze addition of arylsulfonamides to styrenes and olefins. Amination of terpyridines with Pd catalysis.
Racemic version of BINAP.
reagent type: ligand
reaction type: Acylations, Arylations, Buchwald-Hartwig Cross Coupling , C-C Bond Formation, Decarboxylations, Stille Coupling